Hamm, Christin M. and Schäfer, Timo and Zhang, Hongbin and Birkel, Christina S. (2016):
Non-conventional Synthesis of the 413 MAX Phase V4AlC3.
642, In: Zeitschrift für anorganische und allgemeine Chemie, (23), WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim, pp. 1397-1401, ISSN 00442313, DOI: 10.1002/zaac.201600370,
[Online-Edition: https://doi.org/10.1002/zaac.201600370],
[Article]
Abstract
V4AlC3 belongs to the intriguing class of materials of so-called MAX phases that are ternary carbides and nitrides crystallizing in a layered crystal structure with space group P63/mmc. They exhibit excellent mechanical properties combining characteristics of metals as well as ceramics. The synthesis of single-phase products is far from being trivial since high temperatures are required, while most competing phases are also thermodynamically stable. Herein, we show the non-conventional solid-state preparation by susceptor-assisted microwave heating within 60 min. The crystallinity of the nearly single-phase compound is enhanced by subsequent densification using the spark plasma sintering technique. The formation mechanism of V4AlC3 is investigated by means of thermoanalysis. Intermediate as well as final products are characterized by powder X-ray diffraction techniques.
| Item Type: | Article |
|---|---|
| Erschienen: | 2016 |
| Creators: | Hamm, Christin M. and Schäfer, Timo and Zhang, Hongbin and Birkel, Christina S. |
| Title: | Non-conventional Synthesis of the 413 MAX Phase V4AlC3 |
| Language: | English |
| Abstract: | V4AlC3 belongs to the intriguing class of materials of so-called MAX phases that are ternary carbides and nitrides crystallizing in a layered crystal structure with space group P63/mmc. They exhibit excellent mechanical properties combining characteristics of metals as well as ceramics. The synthesis of single-phase products is far from being trivial since high temperatures are required, while most competing phases are also thermodynamically stable. Herein, we show the non-conventional solid-state preparation by susceptor-assisted microwave heating within 60 min. The crystallinity of the nearly single-phase compound is enhanced by subsequent densification using the spark plasma sintering technique. The formation mechanism of V4AlC3 is investigated by means of thermoanalysis. Intermediate as well as final products are characterized by powder X-ray diffraction techniques. |
| Journal or Publication Title: | Zeitschrift für anorganische und allgemeine Chemie |
| Volume: | 642 |
| Number: | 23 |
| Publisher: | WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
| Uncontrolled Keywords: | MAX phases, V4AlC3, Microwave heating, Spark plasma sintering, Powder X-ray diffraction |
| Divisions: | 11 Department of Materials and Earth Sciences 11 Department of Materials and Earth Sciences > Material Science 11 Department of Materials and Earth Sciences > Material Science > Theory of Magnetic Materials 07 Department of Chemistry 07 Department of Chemistry > Fachgebiet Anorganische Chemie |
| Date Deposited: | 02 Jan 2018 13:14 |
| DOI: | 10.1002/zaac.201600370 |
| Official URL: | https://doi.org/10.1002/zaac.201600370 |
| Additional Information: | Special Issue: Dedicated to Professor Anthony K. Cheetham on the Occasion of his 70th Birthday |
| Funders: | Financial support by the Deutsche Forschungsgemeinschaft (BI 1775/2-1) and the Land Hessen through its excellence program LOEWE "RESPONSE" is gratefully acknowledged. |
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