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Nanoporous Polymers: Bridging the Gap between Molecular and Solid Catalysts?

Rose, Marcus (2014)
Nanoporous Polymers: Bridging the Gap between Molecular and Solid Catalysts?
In: ChemCatChem, 6 (5)
doi: 10.1002/cctc.201301071
Artikel, Bibliographie

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Kurzbeschreibung (Abstract)

The combination of the advantageous properties of molecular and solid catalysts is considered the “Holy Grail” in catalysis research. Great potential is provided by nanoporous polymers. Chemically well-defined moieties in combination with a high stability render these materials suitable as catalyst supports for liquid-phase and even aqueous-phase catalytic processes, especially regarding the transition from fossil resources to renewable resources. In this Minireview, recent developments are summarized, covering the three main approaches: solid metal-free organocatalysts, immobilized molecular catalyst species, and supported metal nanoparticles and clusters. Their potential is evaluated and the question as to whether nanoporous polymers can bridge the gap between homogeneous and heterogeneous catalysis is critically discussed.

Typ des Eintrags: Artikel
Erschienen: 2014
Autor(en): Rose, Marcus
Art des Eintrags: Bibliographie
Titel: Nanoporous Polymers: Bridging the Gap between Molecular and Solid Catalysts?
Sprache: Englisch
Publikationsjahr: 2014
Ort: Weinheim
Verlag: Wiley-VCH
Titel der Zeitschrift, Zeitung oder Schriftenreihe: ChemCatChem
Jahrgang/Volume einer Zeitschrift: 6
(Heft-)Nummer: 5
DOI: 10.1002/cctc.201301071
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Kurzbeschreibung (Abstract):

The combination of the advantageous properties of molecular and solid catalysts is considered the “Holy Grail” in catalysis research. Great potential is provided by nanoporous polymers. Chemically well-defined moieties in combination with a high stability render these materials suitable as catalyst supports for liquid-phase and even aqueous-phase catalytic processes, especially regarding the transition from fossil resources to renewable resources. In this Minireview, recent developments are summarized, covering the three main approaches: solid metal-free organocatalysts, immobilized molecular catalyst species, and supported metal nanoparticles and clusters. Their potential is evaluated and the question as to whether nanoporous polymers can bridge the gap between homogeneous and heterogeneous catalysis is critically discussed.

Fachbereich(e)/-gebiet(e): 07 Fachbereich Chemie
07 Fachbereich Chemie > Ernst-Berl-Institut
07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie
07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie > Technische Chemie II
Hinterlegungsdatum: 07 Sep 2017 05:53
Letzte Änderung: 19 Feb 2024 09:16
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