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NiCo nanotubes plated on Pd seeds as a designed magnetically recollectable catalyst with high noble metal utilisation

Schaefer, Sandra ; Felix, Eva-Maria ; Muench, Falk ; Antoni, Markus ; Lohaus, C. ; Brötz, Joachim ; Kunz, Ulrike ; Gärtner, I. ; Ensinger, Wolfgang (2016)
NiCo nanotubes plated on Pd seeds as a designed magnetically recollectable catalyst with high noble metal utilisation.
In: RSC Advances, 6 (74)
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Electroless plating of magnetic materials on catalytically active noble metal seeds is a powerful tool to design highly efficient recyclable catalysts. For the electroless plating procedure of metallic nanotubes in porous polymer templates, a sensitisation and activation process of the template is necessary. Therefore, metallic seeds are created on the surface of the polymer, which then enable the selective heterogeneous nucleation of a metal film on the template's surface. By choosing the metals for seeds and structures wisely, different functional materials can be purposefully combined. In this work magnetically recoverable catalysts were designed, which consist of magnetic NiCo nanotubes as carrier for catalytically active Pd seeds. The synthesised catalyst structures were thoroughly characterised by SEM, TEM, EDX, XRD, XPS, ICP-OES, VSM and then tested in the 4-nitrophenol reduction reaction, which was monitored by UV-Vis spectroscopy. After the reaction the structures were recycled and reused without a decrease in activity.

Typ des Eintrags: Artikel
Erschienen: 2016
Autor(en): Schaefer, Sandra ; Felix, Eva-Maria ; Muench, Falk ; Antoni, Markus ; Lohaus, C. ; Brötz, Joachim ; Kunz, Ulrike ; Gärtner, I. ; Ensinger, Wolfgang
Art des Eintrags: Bibliographie
Titel: NiCo nanotubes plated on Pd seeds as a designed magnetically recollectable catalyst with high noble metal utilisation
Sprache: Englisch
Publikationsjahr: 18 Juli 2016
Verlag: Royal Society of Chemistry Publishing
Titel der Zeitschrift, Zeitung oder Schriftenreihe: RSC Advances
Jahrgang/Volume einer Zeitschrift: 6
(Heft-)Nummer: 74
URL / URN: http://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra10...
Kurzbeschreibung (Abstract):

Electroless plating of magnetic materials on catalytically active noble metal seeds is a powerful tool to design highly efficient recyclable catalysts. For the electroless plating procedure of metallic nanotubes in porous polymer templates, a sensitisation and activation process of the template is necessary. Therefore, metallic seeds are created on the surface of the polymer, which then enable the selective heterogeneous nucleation of a metal film on the template's surface. By choosing the metals for seeds and structures wisely, different functional materials can be purposefully combined. In this work magnetically recoverable catalysts were designed, which consist of magnetic NiCo nanotubes as carrier for catalytically active Pd seeds. The synthesised catalyst structures were thoroughly characterised by SEM, TEM, EDX, XRD, XPS, ICP-OES, VSM and then tested in the 4-nitrophenol reduction reaction, which was monitored by UV-Vis spectroscopy. After the reaction the structures were recycled and reused without a decrease in activity.

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Materialanalytik
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Physikalische Metallkunde
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Strukturforschung
Hinterlegungsdatum: 20 Sep 2016 05:40
Letzte Änderung: 18 Dez 2018 14:50
PPN:
Sponsoren: The authors gratefully acknowledge funding by the LOEWE project RESPONSE of the Hessen State Ministry of Higher Education, Research and the Arts (HMWK).
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