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Synthesis, characterization, molecular structure and supramolecular architectures of some copper(II) complexes derived from salicylaldehyde semicarbazone

Salem, Nahed M. H. and Rashad, Amal R. and El Sayed, Laila and Foro, Sabine and Haase, Wolfgang and Iskander, Magdi F. (2015):
Synthesis, characterization, molecular structure and supramolecular architectures of some copper(II) complexes derived from salicylaldehyde semicarbazone.
In: Inorganica Chimica Acta, ELSEVIER SCIENCE SA, Switzerland, pp. 231-242, 432, ISSN 00201693, [Online-Edition: http://dx.doi.org/10.1016/j.ica.2015.04.019],
[Article]

Abstract

A series of new copper(II) complexes, [Cu(HSalsc)Cl]center dot 1/2H(2)O (1), [{Cu(HSalsc)}(2)(NO3)(2)][{Cu(HSalsc)}(2)- NO3)center dot H2O]NO3 (2), [{Cu(Salsc)}(2)]H2O (3), [Cu(HSalsc)(HIm)]Cl center dot 1/2H(2)O (4), [{Cu(HSalsc)HIm}(2)](NO3)(2) (5) and [Cu(HSalsc)(HIm)]OAc (6) derived from salicylaldehyde semicarbazone (H(2)Salsc) have been prepared and characterized by elemental analysis, infrared and UV-Vis absorption spectra as well as electrospray mass spectra (ESI-MS). The crystal and molecular structure of 1, 2, 5 and 6 have been determined by X-ray single crystal diffraction. The supramolecular architectures in 1, 2, 5 and 6 have been also discussed. (C) 2015 Elsevier B.V. All rights reserved.

Item Type: Article
Erschienen: 2015
Creators: Salem, Nahed M. H. and Rashad, Amal R. and El Sayed, Laila and Foro, Sabine and Haase, Wolfgang and Iskander, Magdi F.
Title: Synthesis, characterization, molecular structure and supramolecular architectures of some copper(II) complexes derived from salicylaldehyde semicarbazone
Language: English
Abstract:

A series of new copper(II) complexes, [Cu(HSalsc)Cl]center dot 1/2H(2)O (1), [{Cu(HSalsc)}(2)(NO3)(2)][{Cu(HSalsc)}(2)- NO3)center dot H2O]NO3 (2), [{Cu(Salsc)}(2)]H2O (3), [Cu(HSalsc)(HIm)]Cl center dot 1/2H(2)O (4), [{Cu(HSalsc)HIm}(2)](NO3)(2) (5) and [Cu(HSalsc)(HIm)]OAc (6) derived from salicylaldehyde semicarbazone (H(2)Salsc) have been prepared and characterized by elemental analysis, infrared and UV-Vis absorption spectra as well as electrospray mass spectra (ESI-MS). The crystal and molecular structure of 1, 2, 5 and 6 have been determined by X-ray single crystal diffraction. The supramolecular architectures in 1, 2, 5 and 6 have been also discussed. (C) 2015 Elsevier B.V. All rights reserved.

Journal or Publication Title: Inorganica Chimica Acta
Volume: 432
Publisher: ELSEVIER SCIENCE SA, Switzerland
Uncontrolled Keywords: Salicylaldehyde semicarbazone Cu(II) complexes, Synthesis, Characterization, X-ray crystal structures, Supramolecular architectures
Divisions: 11 Department of Materials and Earth Sciences > Material Science
11 Department of Materials and Earth Sciences > Material Science > Structure Research
07 Department of Chemistry
11 Department of Materials and Earth Sciences
Date Deposited: 19 Jan 2016 12:50
Official URL: http://dx.doi.org/10.1016/j.ica.2015.04.019
Identification Number: doi:10.1016/j.ica.2015.04.019
Funders: Thanks are due to DFG (1.8131e-2/09) for supporting this bilateral project.
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