Zakhozheva, Marina ; Schmitt, Ljubomira A. ; Acosta, Matias ; Jo, Wook ; Rödel, Jürgen ; Kleebe, Hans-Joachim (2014):
In situ electric field induced domain evolution in Ba(Zr0.2Ti0.8)O3-0.3(Ba0.7Ca0.3)TiO3 ferroelectrics.
In: Applied Physics Letters, 105 (11), pp. 112904-1-112904-4. AIP Publishing, ISSN 0003-6951,
DOI: 10.1063/1.4896048,
[Article]
Abstract
In this work, the lead-free Ba(Zr0.2Ti0.8)O3-0.3(Ba0.7Ca0.3)TiO3 piezoelectric ceramic was investigated in situ under an applied electric field by transmission electron microscopy. Significant changes in domain morphology of the studied material have been observed under an applied electric field. During the poling process, the domain configurations disappeared, forming a single-domain state. This multi- to single-domain state transition occurred with the formation of an intermediate nanodomain state. After removing the electric field, domain configurations reappeared. Selected area electron diffraction during electrical poling gave no indication of any structural changes as for example reflection splitting. Rather, a contribution of the extrinsic effect to the piezoelectric response of the Ba(Zr0.2Ti0.8)O3-0.3(Ba0.7Ca0.3)TiO3 was found to be dominant.
Item Type: | Article |
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Erschienen: | 2014 |
Creators: | Zakhozheva, Marina ; Schmitt, Ljubomira A. ; Acosta, Matias ; Jo, Wook ; Rödel, Jürgen ; Kleebe, Hans-Joachim |
Title: | In situ electric field induced domain evolution in Ba(Zr0.2Ti0.8)O3-0.3(Ba0.7Ca0.3)TiO3 ferroelectrics |
Language: | English |
Abstract: | In this work, the lead-free Ba(Zr0.2Ti0.8)O3-0.3(Ba0.7Ca0.3)TiO3 piezoelectric ceramic was investigated in situ under an applied electric field by transmission electron microscopy. Significant changes in domain morphology of the studied material have been observed under an applied electric field. During the poling process, the domain configurations disappeared, forming a single-domain state. This multi- to single-domain state transition occurred with the formation of an intermediate nanodomain state. After removing the electric field, domain configurations reappeared. Selected area electron diffraction during electrical poling gave no indication of any structural changes as for example reflection splitting. Rather, a contribution of the extrinsic effect to the piezoelectric response of the Ba(Zr0.2Ti0.8)O3-0.3(Ba0.7Ca0.3)TiO3 was found to be dominant. |
Journal or Publication Title: | Applied Physics Letters |
Journal volume: | 105 |
Number: | 11 |
Publisher: | AIP Publishing |
Uncontrolled Keywords: | Piezoelectric fields, Piezoelectric materials, Ceramics, Transmission electron microscopy, Domain walls |
Divisions: | 11 Department of Materials and Earth Sciences 11 Department of Materials and Earth Sciences > Earth Science 11 Department of Materials and Earth Sciences > Earth Science > Geo-Material-Science 11 Department of Materials and Earth Sciences > Material Science 11 Department of Materials and Earth Sciences > Material Science > Nonmetallic-Inorganic Materials DFG-Collaborative Research Centres (incl. Transregio) DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres Zentrale Einrichtungen DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis > Subproject A1: Manufacturing of ceramic, textured actuators with high strain DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > B - Characterisation DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > B - Characterisation > Subproject B3: Structure Characterization of Piezoelectric Ceramics With Respect to Electrical Fatigue |
Date Deposited: | 29 Oct 2014 10:18 |
DOI: | 10.1063/1.4896048 |
Additional Information: | SFB 595 Cooperation A1, B3 |
Funders: | This work was supported by the Deutsche Forschungsgemeinschaft, Sonderforschungsbereich 595, and by the AdRIA Hesse State Center for Adaptronics. |
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