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Secondary phosphine oxides as pre-ligands for nanoparticle stabilization

Rafter, E. and Gutmann, T. and Low, F. and Buntkowsky, G. and Philippot, K. and Chaudret, B. and van Leeuwen, P. W. N. M. (2013):
Secondary phosphine oxides as pre-ligands for nanoparticle stabilization.
3, In: Catalysis Science & Technology, (3), pp. 595-599, [Online-Edition: http://apps.webofknowledge.com/full_record.do?product=WOS&se...],
[Article]

Abstract

The synthesis of ruthenium nanoparticles (RuNPs) using secondary phosphine oxides (SPOs) as ligands is reported. These easily accessible ligands allow the formation of small nanoparticles in the size range of 1-2 nm which display a high efficiency for hydrogenation of aromatics with TOFs up to 2700 mol h(-1).

Item Type: Article
Erschienen: 2013
Creators: Rafter, E. and Gutmann, T. and Low, F. and Buntkowsky, G. and Philippot, K. and Chaudret, B. and van Leeuwen, P. W. N. M.
Title: Secondary phosphine oxides as pre-ligands for nanoparticle stabilization
Language: English
Abstract:

The synthesis of ruthenium nanoparticles (RuNPs) using secondary phosphine oxides (SPOs) as ligands is reported. These easily accessible ligands allow the formation of small nanoparticles in the size range of 1-2 nm which display a high efficiency for hydrogenation of aromatics with TOFs up to 2700 mol h(-1).

Journal or Publication Title: Catalysis Science & Technology
Volume: 3
Number: 3
Uncontrolled Keywords: diphenylphosphinous acid complexes solid-state nmr ruthenium nanoparticles h-2 nmr hydrogen hydroformylation preligands catalysis activation nucleation
Divisions: 07 Department of Chemistry
07 Department of Chemistry > Physical Chemistry
Date Deposited: 27 Oct 2014 20:47
Official URL: http://apps.webofknowledge.com/full_record.do?product=WOS&se...
Additional Information:

087SE Times Cited:8 Cited References Count:46

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