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Solid-state NMR concepts for the investigation of supported transition metal catalysts and nanoparticles

Gutmann, T. and Grünberg, A. and Rothermel, N. and Werner, M. and Srour, M. and Abdulhussain, S. and Tan, S. L. and Xu, Y. P. and Breitzke, H. and Buntkowsky, G. (2013):
Solid-state NMR concepts for the investigation of supported transition metal catalysts and nanoparticles.
55-56, In: Solid State Nuclear Magnetic Resonance, pp. 1-11, [Online-Edition: http://apps.webofknowledge.com/full_record.do?product=WOS&se...],
[Article]

Abstract

In recent years, solid-state NMR spectroscopy has evolved into an important characterization tool for the study of solid catalysts and chemical processes on their surface. This interest is mainly triggered by the need of environmentally benign organic transformations ("green chemistry"), which has resulted in a large number of new catalytically active hybrid materials, which are organized on the meso- and nanoscale. Typical examples of these catalysts are supported homogeneous transition metal catalysts or transition metal nanoparticles (MNPs). Solid-state NMR spectroscopy is able to characterize both the structures of these materials and the chemical processes on the catalytic surface. This article presents recent trends both on the characterization of immobilized homogeneous transition metal catalysts and on the characterization of surface species on transition metal surfaces. (C) 2013 Elsevier Inc. All rights reserved.

Item Type: Article
Erschienen: 2013
Creators: Gutmann, T. and Grünberg, A. and Rothermel, N. and Werner, M. and Srour, M. and Abdulhussain, S. and Tan, S. L. and Xu, Y. P. and Breitzke, H. and Buntkowsky, G.
Title: Solid-state NMR concepts for the investigation of supported transition metal catalysts and nanoparticles
Language: English
Abstract:

In recent years, solid-state NMR spectroscopy has evolved into an important characterization tool for the study of solid catalysts and chemical processes on their surface. This interest is mainly triggered by the need of environmentally benign organic transformations ("green chemistry"), which has resulted in a large number of new catalytically active hybrid materials, which are organized on the meso- and nanoscale. Typical examples of these catalysts are supported homogeneous transition metal catalysts or transition metal nanoparticles (MNPs). Solid-state NMR spectroscopy is able to characterize both the structures of these materials and the chemical processes on the catalytic surface. This article presents recent trends both on the characterization of immobilized homogeneous transition metal catalysts and on the characterization of surface species on transition metal surfaces. (C) 2013 Elsevier Inc. All rights reserved.

Journal or Publication Title: Solid State Nuclear Magnetic Resonance
Volume: 55-56
Uncontrolled Keywords: solid state nmr heterogeneous catalysis transition metal nanoparticles h-2 solid-state nmr immobilized catalyst laser-polarized xenon dynamic nuclear-polarization stabilized ruthenium nanoparticles surface organometallic chemistry rhodium hydrogenation catalysts inorganic hybrid materials cross-relaxation dynamics fischer-tropsch synthesis angle-spinning techniques mesoporous silica
Divisions: 07 Department of Chemistry
07 Department of Chemistry > Physical Chemistry
Date Deposited: 27 Oct 2014 20:41
Official URL: http://apps.webofknowledge.com/full_record.do?product=WOS&se...
Additional Information:

254AQ Times Cited:2 Cited References Count:145

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