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Optical Nuclear-Polarization of Deuterium Spins - Mechanisms and Applications in Solid-State NMR

Allgeier, J. and Buntkowsky, G. and Hentrich, S. and Hoffmann, W. and Vieth, H. M. (1992):
Optical Nuclear-Polarization of Deuterium Spins - Mechanisms and Applications in Solid-State NMR.
In: Israel Journal of Chemistry, pp. 205-213, 32, (2-3), [Online-Edition: http://apps.webofknowledge.com/full_record.do?product=WOS&se...],
[Article]

Abstract

A gain in detection sensitivity of more than three orders of magnitude has been achieved in high resolution solid state H-2 NMR of monocrystalline systems by applying optical nuclear polarization (ONP) via excited triplet states. The method is demonstrated for crystals of fluorene doped with optically active guest molecules which have localized triplet states and for the 1:1 mixed crystal of anthracene/tetracyanobenzene with excitonic states. The factors determining the efficiency of ONP are discussed and compared to the case of proton spin systems.

Item Type: Article
Erschienen: 1992
Creators: Allgeier, J. and Buntkowsky, G. and Hentrich, S. and Hoffmann, W. and Vieth, H. M.
Title: Optical Nuclear-Polarization of Deuterium Spins - Mechanisms and Applications in Solid-State NMR
Language: English
Abstract:

A gain in detection sensitivity of more than three orders of magnitude has been achieved in high resolution solid state H-2 NMR of monocrystalline systems by applying optical nuclear polarization (ONP) via excited triplet states. The method is demonstrated for crystals of fluorene doped with optically active guest molecules which have localized triplet states and for the 1:1 mixed crystal of anthracene/tetracyanobenzene with excitonic states. The factors determining the efficiency of ONP are discussed and compared to the case of proton spin systems.

Journal or Publication Title: Israel Journal of Chemistry
Volume: 32
Number: 2-3
Uncontrolled Keywords: doped fluorene crystals charge-transfer complex radical pair formation induction spectroscopy hydrogen abstraction aromatic crystals excited-states tetracyanobenzene consequence anthracene
Divisions: 07 Department of Chemistry
07 Department of Chemistry > Physical Chemistry
Date Deposited: 27 Oct 2014 20:33
Official URL: http://apps.webofknowledge.com/full_record.do?product=WOS&se...
Additional Information:

Kt517 Times Cited:5 Cited References Count:38

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