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Highly cis-selective and lead-free hydrogenation of 2-hexyne by a supported Pd catalyst with an ionic-liquid layer

Schwab, Frederick and Weidler, Natascha and Lucas, Martin and Claus, Peter (2014):
Highly cis-selective and lead-free hydrogenation of 2-hexyne by a supported Pd catalyst with an ionic-liquid layer.
In: Chemical Communications, pp. 10406-10408, 50, (72), ISSN 1359-7345, [Online-Edition: http://dx.doi.org/10.1039/C4CC04183F],
[Article]

Abstract

A simple Pd/SiO2 catalyst which was modified with the ionic liquid [BMPL][DCA] gave an excellent yield of 88% towards cis-2-hexene in the stereoselective hydrogenation of 2-hexyne. The catalyst outperforms, even at full conversion, the commonly used lead-poisoned, toxic Lindlar catalyst and supported colloidal-based Pd as well.

Item Type: Article
Erschienen: 2014
Creators: Schwab, Frederick and Weidler, Natascha and Lucas, Martin and Claus, Peter
Title: Highly cis-selective and lead-free hydrogenation of 2-hexyne by a supported Pd catalyst with an ionic-liquid layer
Language: English
Abstract:

A simple Pd/SiO2 catalyst which was modified with the ionic liquid [BMPL][DCA] gave an excellent yield of 88% towards cis-2-hexene in the stereoselective hydrogenation of 2-hexyne. The catalyst outperforms, even at full conversion, the commonly used lead-poisoned, toxic Lindlar catalyst and supported colloidal-based Pd as well.

Journal or Publication Title: Chemical Communications
Volume: 50
Number: 72
Divisions: 07 Department of Chemistry
07 Department of Chemistry > Fachgebiet Technische Chemie
07 Department of Chemistry > Fachgebiet Technische Chemie > Technische Chemie II
Date Deposited: 17 Sep 2014 16:17
Official URL: http://dx.doi.org/10.1039/C4CC04183F
Identification Number: doi:10.1039/C4CC04183F
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