Muench, Falk ; Lauterbach, Stefan ; Kleebe, Hans-Joachim ; Ensinger, Wolfgang (2012)
Deposition of Nanofilms inside a Polymer Template:Formation of Metal Nanotubes.
In: e-Journal of Surface Science and Nanotechnology, 10
doi: 10.1380/ejssnt.2012.578
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
Given sufficient synthetic control, electroless plating is a suitable method for the fabrication of precisely defined nanomaterials. This study focuses on requirements which have to be met for the homogeneous and conformal electroless metal deposition within ion track etched polymer templates, allowing the fabrication of high aspect ratio metal nanotubes. Namely, the effects of (i) the seed density of the substrate, (ii) the surface-selectivity of the plating reaction and (iii) the deposition speed and the grain size of the resulting deposit are examined, and strategies to modify these characteristics in order to improve nanotube formation are illustrated. With optimized procedures, Ag, Au and Pt nanotubes were obtained. As an application example, metal nanotube membranes were utilized as flow-through microreactors, catalyzing the reduction of 4-nitrophenol with sodium borohydride. By partial exchange of Ag precursor structures with Pt, roughened Ag-Pt nanotubes with significantly improved activity were obtained. DOI: 10.1380/ejssnt.2012.578]
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2012 |
| Autor(en): | Muench, Falk ; Lauterbach, Stefan ; Kleebe, Hans-Joachim ; Ensinger, Wolfgang |
| Art des Eintrags: | Bibliographie |
| Titel: | Deposition of Nanofilms inside a Polymer Template:Formation of Metal Nanotubes |
| Sprache: | Englisch |
| Publikationsjahr: | 2012 |
| Verlag: | The Surface Science Society of Japan |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | e-Journal of Surface Science and Nanotechnology |
| Jahrgang/Volume einer Zeitschrift: | 10 |
| DOI: | 10.1380/ejssnt.2012.578 |
| Kurzbeschreibung (Abstract): | Given sufficient synthetic control, electroless plating is a suitable method for the fabrication of precisely defined nanomaterials. This study focuses on requirements which have to be met for the homogeneous and conformal electroless metal deposition within ion track etched polymer templates, allowing the fabrication of high aspect ratio metal nanotubes. Namely, the effects of (i) the seed density of the substrate, (ii) the surface-selectivity of the plating reaction and (iii) the deposition speed and the grain size of the resulting deposit are examined, and strategies to modify these characteristics in order to improve nanotube formation are illustrated. With optimized procedures, Ag, Au and Pt nanotubes were obtained. As an application example, metal nanotube membranes were utilized as flow-through microreactors, catalyzing the reduction of 4-nitrophenol with sodium borohydride. By partial exchange of Ag precursor structures with Pt, roughened Ag-Pt nanotubes with significantly improved activity were obtained. DOI: 10.1380/ejssnt.2012.578] |
| Freie Schlagworte: | Catalysis, Electroless plating, Metal na-notubes, Nano structure chemistry, Polycrystalline thin films, processing and fabrication |
| Zusätzliche Informationen: | This paper was presented at the 16th International Conference on Solid Films and Surfaces (ICSFS-16), University of Genoa, Genoa, Italy, 1-6 July, 2012. |
| Fachbereich(e)/-gebiet(e): | 11 Fachbereich Material- und Geowissenschaften > Geowissenschaften > Fachgebiet Geomaterialwissenschaft 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Materialanalytik 11 Fachbereich Material- und Geowissenschaften > Geowissenschaften 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft 11 Fachbereich Material- und Geowissenschaften |
| Hinterlegungsdatum: | 19 Nov 2012 12:24 |
| Letzte Änderung: | 05 Mär 2013 10:03 |
| PPN: | |
| Sponsoren: | Supply of Au solution by Schütz Dental GmbH is gratefully acknowledged. |
| Export: | |
| Suche nach Titel in: | TUfind oder in Google |
 |
Frage zum Eintrag |
Optionen (nur für Redakteure)
 |
Redaktionelle Details anzeigen |
Drucken
Impressum