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Influence of Ti-Based Fillers on the Thermal Decomposition and Phase Development of Polysiloxane Derived Materials

Hönack, F. ; Riedel, R. (2003):
Influence of Ti-Based Fillers on the Thermal Decomposition and Phase Development of Polysiloxane Derived Materials.
In: Advanced Engineering Materials, 5 (3), pp. 122-125. Wiley, ISSN 14381656,
[Article]

Abstract

The addition of carbide-forming filler particles like titanium or TiH2 is a suitable way to adjust the thermal decomposition behavior and the phase development of polysiloxane precursors. Besides TiC as the main crystalline phase formed at 1100°C, titanium silicides are found, but no oxygen-containing crystalline phases. Thermal simultaneous analysis shows that the reaction of filler particles and matrix starts approximately at 300°C.

Item Type: Article
Erschienen: 2003
Creators: Hönack, F. ; Riedel, R.
Title: Influence of Ti-Based Fillers on the Thermal Decomposition and Phase Development of Polysiloxane Derived Materials
Language: English
Abstract:

The addition of carbide-forming filler particles like titanium or TiH2 is a suitable way to adjust the thermal decomposition behavior and the phase development of polysiloxane precursors. Besides TiC as the main crystalline phase formed at 1100°C, titanium silicides are found, but no oxygen-containing crystalline phases. Thermal simultaneous analysis shows that the reaction of filler particles and matrix starts approximately at 300°C.

Journal or Publication Title: Advanced Engineering Materials
Journal volume: 5
Number: 3
Publisher: Wiley
Uncontrolled Keywords: Filler particles, Ti-based, Polysiloxanes, Preceramic polymers
Divisions: 11 Department of Materials and Earth Sciences > Material Science > Dispersive Solids
11 Department of Materials and Earth Sciences > Material Science
11 Department of Materials and Earth Sciences
Date Deposited: 23 Apr 2012 11:28
Official URL: http://dx.doi.org/10.1002/adem.200390018
Identification Number: doi:10.1002/adem.200390018
Funders: The work was financially supported by Sintercast AG, Sweden, Ford Motor Company, UK, and Eisenwerke Brühl GmbH, Germany, as well as by the Fonds der Chemischen Industrie, Germany.
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