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Alkalicyamelurates, M3[C6N7O3].xH2O, M = Li, Na, K, Rb, Cs: UV-luminescent and thermally very stable ionic tri-s-triazine derivatives.

Horvath-Bordon, E. and Kroke, E. and Svoboda, I. and Fuess, H. and Riedel, R. and Neeraj, S. and Cheetham, A. K. (2004):
Alkalicyamelurates, M3[C6N7O3].xH2O, M = Li, Na, K, Rb, Cs: UV-luminescent and thermally very stable ionic tri-s-triazine derivatives.
In: Dalton Transactions, (22), RSC Publishing, pp. 3900-8, [Article]

Abstract

Cyamelurates are salts of cyameluric acid, a derivative of tri-s-triazine (1,3,4,6,7,9-hexaazacyclo[3.3.3]azine or s-heptazine). These compounds are thermally very stable and possess interesting structural and optical properties. Only very few tri-s-triazine derivatives have been reported in the literature. The water-soluble alkali cyamelurates were extensively characterized using NMR, FTIR, Raman, UV, luminescence spectroscopy and elemental analysis. In addition, the single crystal X-ray structure analyses of the four hydrates of lithium, sodium, potassium and rubidium cyamelurates (Li(3)[C(6)N(7)O(3)].6H(2)O; Na(3)[C(6)N(7)O(3)].4.5H(2)O; K(3)[C(6)N(7)O(3)].3H(2)O; Rb(3)[C(6)N(7)O(3)].3H(2)O) are presented. Thermogravimetric analysis shows that the dehydrated salts start to decompose at temperatures above 500 degrees C. The thermal stability does not depend on the cations which is in contrast to the analogous s-triazine salts, i.e. the alkali cyanurates M(3)[C(3)N(3)O(3)]. The photoluminescence spectra indicate a very strong solid state UV-emission with maxima between 280 and 400 nm.

Item Type: Article
Erschienen: 2004
Creators: Horvath-Bordon, E. and Kroke, E. and Svoboda, I. and Fuess, H. and Riedel, R. and Neeraj, S. and Cheetham, A. K.
Title: Alkalicyamelurates, M3[C6N7O3].xH2O, M = Li, Na, K, Rb, Cs: UV-luminescent and thermally very stable ionic tri-s-triazine derivatives.
Language: English
Abstract:

Cyamelurates are salts of cyameluric acid, a derivative of tri-s-triazine (1,3,4,6,7,9-hexaazacyclo[3.3.3]azine or s-heptazine). These compounds are thermally very stable and possess interesting structural and optical properties. Only very few tri-s-triazine derivatives have been reported in the literature. The water-soluble alkali cyamelurates were extensively characterized using NMR, FTIR, Raman, UV, luminescence spectroscopy and elemental analysis. In addition, the single crystal X-ray structure analyses of the four hydrates of lithium, sodium, potassium and rubidium cyamelurates (Li(3)[C(6)N(7)O(3)].6H(2)O; Na(3)[C(6)N(7)O(3)].4.5H(2)O; K(3)[C(6)N(7)O(3)].3H(2)O; Rb(3)[C(6)N(7)O(3)].3H(2)O) are presented. Thermogravimetric analysis shows that the dehydrated salts start to decompose at temperatures above 500 degrees C. The thermal stability does not depend on the cations which is in contrast to the analogous s-triazine salts, i.e. the alkali cyanurates M(3)[C(3)N(3)O(3)]. The photoluminescence spectra indicate a very strong solid state UV-emission with maxima between 280 and 400 nm.

Journal or Publication Title: Dalton Transactions
Number: 22
Publisher: RSC Publishing
Divisions: 11 Department of Materials and Earth Sciences > Material Science > Dispersive Solids
11 Department of Materials and Earth Sciences > Material Science > Structure Research
11 Department of Materials and Earth Sciences > Material Science
11 Department of Materials and Earth Sciences
Date Deposited: 23 Apr 2012 09:02
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