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The diffusion of carbon atoms inside carbon nanotubes

Gan, Yanjie ; Kotakoski, J. ; Krasheninnikov, A. V. ; Nordlund, K. ; Banhart, F. (2008)
The diffusion of carbon atoms inside carbon nanotubes.
In: New Journal of Physics, 10 (2)
doi: 10.1088/1367-2630/10/2/023022
Artikel, Bibliographie

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Kurzbeschreibung (Abstract)

We combine electron irradiation experiments in a transmission electron microscope with kinetic Monte Carlo simulations to determine the mobility of interstitial carbon atoms in single-walled carbon nanotubes. We measure the irradiation dose necessary to cut nanotubes repeatedly with a focused electron beam as a function of the separation between the cuts and at different temperatures. As the cutting speed is related to the migration of displaced carbon atoms trapped inside the tube and to their recombination with vacancies, we obtain information about the mobility of the trapped atoms and estimate their migration barrier to be about 0.25 eV. This is an experimental confirmation of the remarkably high mobility of interstitial atoms inside carbon nanotubes, which shows that nanotubes have potential applications as pipelines for the transport of carbon atoms.

Typ des Eintrags: Artikel
Erschienen: 2008
Autor(en): Gan, Yanjie ; Kotakoski, J. ; Krasheninnikov, A. V. ; Nordlund, K. ; Banhart, F.
Art des Eintrags: Bibliographie
Titel: The diffusion of carbon atoms inside carbon nanotubes
Sprache: Englisch
Publikationsjahr: 2 Februar 2008
Verlag: IOP Publishing
Titel der Zeitschrift, Zeitung oder Schriftenreihe: New Journal of Physics
Jahrgang/Volume einer Zeitschrift: 10
(Heft-)Nummer: 2
DOI: 10.1088/1367-2630/10/2/023022
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Kurzbeschreibung (Abstract):

We combine electron irradiation experiments in a transmission electron microscope with kinetic Monte Carlo simulations to determine the mobility of interstitial carbon atoms in single-walled carbon nanotubes. We measure the irradiation dose necessary to cut nanotubes repeatedly with a focused electron beam as a function of the separation between the cuts and at different temperatures. As the cutting speed is related to the migration of displaced carbon atoms trapped inside the tube and to their recombination with vacancies, we obtain information about the mobility of the trapped atoms and estimate their migration barrier to be about 0.25 eV. This is an experimental confirmation of the remarkably high mobility of interstitial atoms inside carbon nanotubes, which shows that nanotubes have potential applications as pipelines for the transport of carbon atoms.

ID-Nummer: Artikel-ID: 023022
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Materialmodellierung
Hinterlegungsdatum: 28 Feb 2012 15:17
Letzte Änderung: 06 Mär 2024 06:19
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Sponsoren: We thank the DAAD and ETC for an exchange grant (D/05/51651) and the Academy of Finland for support through several projects and the Centre of Excellence programme., We are also indebted to the Finnish Center for Scientific Computing for generous grants of computer time.
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