Erdem, Emre ; Eichel, Rüdiger-A.
Hrsg.: Lallart, Mickael (2011)
Impact of Defect Structure on ’Bulk’ and Nano-Scale Ferroelectrics.
In: Ferroelectrics - Characterization and Modeling
Buchkapitel, Bibliographie
Kurzbeschreibung (Abstract)
Ferroelectric materials offer a wide range of dedicated physical properties such as high dielectric constant, spontaneous polarisation, pyroelectric and piezoelectric effects which can be applied in thin-film non-volatile memories or ‘bulk’ actuators, multi-layer capacitors, thermal sensors and transducers (1–3). In that respect, desiredmaterials properties for specific applicationsmay be tailored by controlling the defect structure bymeans of aliovalent doping, rendering so-termed ’hard’ or ’soft’ piezoelectric materials (4–6). Another important impact on ferroelectric properties results from the confined size in nano-scale architectures (7). At the nanometer scale physical and chemical properties are expected to differ markedly from those of the ’bulk’ material. Owing to a size-driven phase transition, a critical particle size exists below which ferroelectricity does no longer occur (8). In this chapter, we will first outline the nature of the size-driven para-to-ferroelectric phase transition, as well as the concepts of defect chemistry. On that basis, the interplay between confined size at the nano-regime and the development of defect structure will be characterized. The here studied ferroelectric lead titanate nano-powders may be considered as a model system for more complex ferroelectric nano architectures (1; 2). Furthermore, the results discussed here may be transferred to large extent to other important perovskite oxides with divalent A- and tetravalent B-site, such as BaTiO3 or Pb[Zr,Ti]O3 (PZT). The defect chemistry of ferroelectric perovskite oxideswith monovalent A- and pentavalent B-site, such as the [K,Na]NbO3 (KNN) solid solution system, however has shown some important deviations from the defect structure characterized for PZT compounds (9; 10).
| Typ des Eintrags: | Buchkapitel |
|---|---|
| Erschienen: | 2011 |
| Herausgeber: | Lallart, Mickael |
| Autor(en): | Erdem, Emre ; Eichel, Rüdiger-A. |
| Art des Eintrags: | Bibliographie |
| Titel: | Impact of Defect Structure on ’Bulk’ and Nano-Scale Ferroelectrics |
| Sprache: | Englisch |
| Publikationsjahr: | August 2011 |
| Ort: | open access book |
| Verlag: | Intech open access publischer |
| Buchtitel: | Ferroelectrics - Characterization and Modeling |
| Reihe: | smart materials |
| Kurzbeschreibung (Abstract): | Ferroelectric materials offer a wide range of dedicated physical properties such as high dielectric constant, spontaneous polarisation, pyroelectric and piezoelectric effects which can be applied in thin-film non-volatile memories or ‘bulk’ actuators, multi-layer capacitors, thermal sensors and transducers (1–3). In that respect, desiredmaterials properties for specific applicationsmay be tailored by controlling the defect structure bymeans of aliovalent doping, rendering so-termed ’hard’ or ’soft’ piezoelectric materials (4–6). Another important impact on ferroelectric properties results from the confined size in nano-scale architectures (7). At the nanometer scale physical and chemical properties are expected to differ markedly from those of the ’bulk’ material. Owing to a size-driven phase transition, a critical particle size exists below which ferroelectricity does no longer occur (8). In this chapter, we will first outline the nature of the size-driven para-to-ferroelectric phase transition, as well as the concepts of defect chemistry. On that basis, the interplay between confined size at the nano-regime and the development of defect structure will be characterized. The here studied ferroelectric lead titanate nano-powders may be considered as a model system for more complex ferroelectric nano architectures (1; 2). Furthermore, the results discussed here may be transferred to large extent to other important perovskite oxides with divalent A- and tetravalent B-site, such as BaTiO3 or Pb[Zr,Ti]O3 (PZT). The defect chemistry of ferroelectric perovskite oxideswith monovalent A- and pentavalent B-site, such as the [K,Na]NbO3 (KNN) solid solution system, however has shown some important deviations from the defect structure characterized for PZT compounds (9; 10). |
| Zusätzliche Informationen: | SFB 595 B1 |
| Fachbereich(e)/-gebiet(e): | DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > B - Charakterisierung > Teilprojekt B1: EPR Untersuchung von Defekten in ferroelektrischen keramischen Werkstoffen DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung > B - Charakterisierung DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche > SFB 595: Elektrische Ermüdung Zentrale Einrichtungen DFG-Sonderforschungsbereiche (inkl. Transregio) > Sonderforschungsbereiche DFG-Sonderforschungsbereiche (inkl. Transregio) |
| Hinterlegungsdatum: | 29 Aug 2011 10:45 |
| Letzte Änderung: | 05 Mär 2013 09:54 |
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