Kounga, Alain Brice and Zhang, Shan-Tao and Jo, Wook and Granzow, Torsten and Rödel, Jürgen (2008):
Morphotropic phase boundary in (1−x)Bi[sub 0.5]Na[sub 0.5]TiO[sub 3]–xK[sub 0.5]Na[sub 0.5]NbO[sub 3] lead-free piezoceramics.
In: Applied Physics Letters, pp. 222902-1, 92, (22), ISSN 00036951, [Online-Edition: http://dx.doi.org/10.1063/1.2938064],
[Article]
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Abstract
The electromechanical behavior of (1−x)Bi0.5Na0.5TiO3–xK0.5Na0.5NbO3 (BNT-KNN) lead free piezoelectric ceramics is investigated for 0 <= x <= 0.12 to gain insight into the antiferroelectric-ferroelectric (AFE-FE) phase transition on the basis of the giant strain recently observed in BNT-based systems. At x ≈ 0.07, a morphotropic phase boundary (MPB) between a rhombohedral FE phase and a tetragonal AFE phase is found. While the piezoelectric coefficient is largest at this MPB, the total strain further increases with increasing KNN content, indicating the field-induced AFE-FE transition as the main reason for the large strain.
| Item Type: |
Article
|
| Erschienen: |
2008 |
| Creators: |
Kounga, Alain Brice and Zhang, Shan-Tao and Jo, Wook and Granzow, Torsten and Rödel, Jürgen |
| Title: |
Morphotropic phase boundary in (1−x)Bi[sub 0.5]Na[sub 0.5]TiO[sub 3]–xK[sub 0.5]Na[sub 0.5]NbO[sub 3] lead-free piezoceramics |
| Language: |
English |
| Abstract: |
The electromechanical behavior of (1−x)Bi0.5Na0.5TiO3–xK0.5Na0.5NbO3 (BNT-KNN) lead free piezoelectric ceramics is investigated for 0 <= x <= 0.12 to gain insight into the antiferroelectric-ferroelectric (AFE-FE) phase transition on the basis of the giant strain recently observed in BNT-based systems. At x ≈ 0.07, a morphotropic phase boundary (MPB) between a rhombohedral FE phase and a tetragonal AFE phase is found. While the piezoelectric coefficient is largest at this MPB, the total strain further increases with increasing KNN content, indicating the field-induced AFE-FE transition as the main reason for the large strain. |
| Journal or Publication Title: |
Applied Physics Letters |
| Volume: |
92 |
| Number: |
22 |
| Uncontrolled Keywords: |
bismuth compounds, ferroelectric transitions, piezoceramics, piezoelectricity, potassium compounds, sodium compounds |
| Divisions: |
11 Department of Materials and Earth Sciences
11 Department of Materials and Earth Sciences > Material Science
11 Department of Materials and Earth Sciences > Material Science > Nonmetallic-Inorganic Materials
DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis > Subproject A1: Manufacturing of ceramic, textured actuators with high strain
DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > D - Component properties > Subproject D1: Mesoscopic and macroscopic fatigue in doped ferroelectric ceramics
DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis
DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > D - Component properties
DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue
Zentrale Einrichtungen
DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres
DFG-Collaborative Research Centres (incl. Transregio) |
| Date Deposited: |
15 Jun 2011 08:17 |
| Official URL: |
http://dx.doi.org/10.1063/1.2938064 |
| Additional Information: |
SFB 595 Cooperation A1, D1 |
| Identification Number: |
doi:10.1063/1.2938064 |
| Export: |
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