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Temperature-Insensitive Large Strain of (Bi1/2Na1/2)TiO3-(Bi1/2K1/2)TiO3-(K0.5Na0.5)NbO3Lead-Free Piezoceramics

Seifert, Klaus T. P. and Jo, Wook and Rödel, Jürgen (2010):
Temperature-Insensitive Large Strain of (Bi1/2Na1/2)TiO3-(Bi1/2K1/2)TiO3-(K0.5Na0.5)NbO3Lead-Free Piezoceramics.
In: Journal of the American Ceramic Society, pp. 1392-1396, 93, (5), ISSN 00027820, [Online-Edition: http://dx.doi.org/10.1111/j.1551-2916.2009.03573.x],
[Article]

Abstract

The effect of (K0.5Na0.5)NbO3 (KNN) addition on the ferroelectric behavior of (Bi1/2Na1/2)TiO3–(Bi1/2K1/2)TiO3 (BNT–BKT) lead-free piezoceramics was investigated. Polarization and strain hysteresis loops indicate that the ferroelectric order is disrupted significantly with the addition of KNN as a replacement for BNT and the destabilization of the ferroelectric order is accompanied by an enhancement of the unipolar strain, which peaks at a value of ∼0.48% (corresponding to a large signal d33 of ∼600 pm/V) at 1 mol% KNN content. This strain was analyzed as derived from an electrostrictive effect at lower electric fields and a converse piezoelectric effect at higher electric fields. By limiting the electric driving field to exclude the contribution from the converse piezoelectric effect, a temperature-insensitive large-field d33 of ∼250 pm/V up to 200°C was achieved.

Item Type: Article
Erschienen: 2010
Creators: Seifert, Klaus T. P. and Jo, Wook and Rödel, Jürgen
Title: Temperature-Insensitive Large Strain of (Bi1/2Na1/2)TiO3-(Bi1/2K1/2)TiO3-(K0.5Na0.5)NbO3Lead-Free Piezoceramics
Language: English
Abstract:

The effect of (K0.5Na0.5)NbO3 (KNN) addition on the ferroelectric behavior of (Bi1/2Na1/2)TiO3–(Bi1/2K1/2)TiO3 (BNT–BKT) lead-free piezoceramics was investigated. Polarization and strain hysteresis loops indicate that the ferroelectric order is disrupted significantly with the addition of KNN as a replacement for BNT and the destabilization of the ferroelectric order is accompanied by an enhancement of the unipolar strain, which peaks at a value of ∼0.48% (corresponding to a large signal d33 of ∼600 pm/V) at 1 mol% KNN content. This strain was analyzed as derived from an electrostrictive effect at lower electric fields and a converse piezoelectric effect at higher electric fields. By limiting the electric driving field to exclude the contribution from the converse piezoelectric effect, a temperature-insensitive large-field d33 of ∼250 pm/V up to 200°C was achieved.

Journal or Publication Title: Journal of the American Ceramic Society
Volume: 93
Number: 5
Divisions: 11 Department of Materials and Earth Sciences
11 Department of Materials and Earth Sciences > Material Science
11 Department of Materials and Earth Sciences > Material Science > Nonmetallic-Inorganic Materials
DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis > Subproject A1: Manufacturing of ceramic, textured actuators with high strain
DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue > A - Synthesis
DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres > CRC 595: Electrical fatigue
Zentrale Einrichtungen
DFG-Collaborative Research Centres (incl. Transregio) > Collaborative Research Centres
DFG-Collaborative Research Centres (incl. Transregio)
Date Deposited: 20 Jun 2011 09:11
Official URL: http://dx.doi.org/10.1111/j.1551-2916.2009.03573.x
Additional Information:

SFB 595 A1

Identification Number: doi:10.1111/j.1551-2916.2009.03573.x
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