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Can an Electric Field Induce an Antiferroelectric Phase Out of a Ferroelectric Phase?

Tan, Xiaoli ; Frederick, Joshua ; Ma, C. ; Jo, Wook ; Rödel, Jürgen (2010)
Can an Electric Field Induce an Antiferroelectric Phase Out of a Ferroelectric Phase?
In: Physical Review Letters, 105 (25)
doi: 10.1103/PhysRevLett.105.255702
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

It has been widely accepted that electric fields favor the ferroelectric phase with parallel electric dipoles over the antiferroelectric phase. With detailed measurements in polycrystalline ceramics of Pb0.99Nb0.02[(Zr0.57Sn0.43)1-yTiy]0.98O3, we demonstrate in this Letter that electric fields can induce an antiferroelectric phase out of a ferroelectric phase, i.e., trigger an apparently unlikely ferroelectric-to-antiferroelectric phase transition. We suggest that it is caused by the volume contraction from the converse piezoelectric effect at the coercive field with a reversed polarity.

Typ des Eintrags: Artikel
Erschienen: 2010
Autor(en): Tan, Xiaoli ; Frederick, Joshua ; Ma, C. ; Jo, Wook ; Rödel, Jürgen
Art des Eintrags: Bibliographie
Titel: Can an Electric Field Induce an Antiferroelectric Phase Out of a Ferroelectric Phase?
Sprache: Englisch
Publikationsjahr: Dezember 2010
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Physical Review Letters
Jahrgang/Volume einer Zeitschrift: 105
(Heft-)Nummer: 25
DOI: 10.1103/PhysRevLett.105.255702
Kurzbeschreibung (Abstract):

It has been widely accepted that electric fields favor the ferroelectric phase with parallel electric dipoles over the antiferroelectric phase. With detailed measurements in polycrystalline ceramics of Pb0.99Nb0.02[(Zr0.57Sn0.43)1-yTiy]0.98O3, we demonstrate in this Letter that electric fields can induce an antiferroelectric phase out of a ferroelectric phase, i.e., trigger an apparently unlikely ferroelectric-to-antiferroelectric phase transition. We suggest that it is caused by the volume contraction from the converse piezoelectric effect at the coercive field with a reversed polarity.

Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Nichtmetallisch-Anorganische Werkstoffe
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften
Hinterlegungsdatum: 17 Jun 2011 11:31
Letzte Änderung: 05 Mär 2013 09:48
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