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Synthesis, Reactions and Properties of Iron, Cobalt and Nickel Complexes Containing some [P,S]-chelating Ligands and Trimethylphosphine

Bennour, Hamdi (2010):
Synthesis, Reactions and Properties of Iron, Cobalt and Nickel Complexes Containing some [P,S]-chelating Ligands and Trimethylphosphine.
Darmstadt, Technische Universität, TU Darmstadt, [Online-Edition: urn:nbn:de:tuda-tuprints-21071],
[Ph.D. Thesis]

Abstract

The work submitted here is concerned with the synthesis and characterization of new [P,S]-chelate complexes of the iron, cobalt and nickel, supported by trimethylphosphine ligands and with an investigation of chemical responses of these systems. Among the new compounds of these metals are stable hydrido and methyl metal compounds in low and high oxidation states which are of particular interest as models for homogeneous catalysis.

Item Type: Ph.D. Thesis
Erschienen: 2010
Creators: Bennour, Hamdi
Title: Synthesis, Reactions and Properties of Iron, Cobalt and Nickel Complexes Containing some [P,S]-chelating Ligands and Trimethylphosphine
Language: English
Abstract:

The work submitted here is concerned with the synthesis and characterization of new [P,S]-chelate complexes of the iron, cobalt and nickel, supported by trimethylphosphine ligands and with an investigation of chemical responses of these systems. Among the new compounds of these metals are stable hydrido and methyl metal compounds in low and high oxidation states which are of particular interest as models for homogeneous catalysis.

Place of Publication: Darmstadt
Publisher: Technische Universität
Uncontrolled Keywords: Synthesis, Iron, Cobalt, Nickel, Complex, Trimethylphosphine
Divisions: 07 Department of Chemistry > Fachgebiet Anorganische Chemie
07 Department of Chemistry
Date Deposited: 30 Mar 2010 06:08
Official URL: urn:nbn:de:tuda-tuprints-21071
License: only the rights of use according to UrhG
Referees: Klein, Prof. Dr. H.-F. and Schneider, Prof. Dr. J. J.
Refereed / Verteidigung / mdl. Prüfung: 8 February 2010
Alternative Abstract:
Alternative abstract Language
Die hier vorgelegte Arbeit beschreibt Synthesen und Charakterisierung neuer [P,S]-chelate von Eisen, Cobalt und Nickel, die von Trimethylphosphin-Liganden gestützt werden, und die Untersuchung der chemischen Eigenschaften dieser Systeme. Unter den neuen Verbindungen ragen stabile Hydrido- und Methylmetall-Komplexe in hohen und niedrigen Oxidationsstufen heraus, die als Modellverbindungen für die Homogene Katalyse von besonderem Interesse sind.German
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