Steffan, Martin ; Lucas, Martin ; Brandner, Armin ; Wollny, Mathis ; Oldenburg, Nils ; Claus, Peter (2007)
Selective hydrogenation of citral in an organic solvent, in a ionic liquid, and in substance.
In: Chemical Engineering & Technology, 30 (4)
doi: 10.1002/ceat.200600286
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
It is investigated whether the catalyst system Ag-In/SiO₂ can be applied in the selective hydrogenation of citral, with the aim of synthesizing the acyclic, allylic terpene alcohols geraniol/nerol with high selectivity and space-time yield. In addition, as liquid-phase hydrogenations are often also influenced by the choice of solvent, it is of interest to know how the solvent, in particular in terms of its polarity and hydrogen solubility, affects the activity and the selectivity of catalysts during hydrogenation of the α,β-unsaturated aldehyde citral.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2007 |
| Autor(en): | Steffan, Martin ; Lucas, Martin ; Brandner, Armin ; Wollny, Mathis ; Oldenburg, Nils ; Claus, Peter |
| Art des Eintrags: | Bibliographie |
| Titel: | Selective hydrogenation of citral in an organic solvent, in a ionic liquid, and in substance |
| Sprache: | Englisch |
| Publikationsjahr: | April 2007 |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Chemical Engineering & Technology |
| Jahrgang/Volume einer Zeitschrift: | 30 |
| (Heft-)Nummer: | 4 |
| DOI: | 10.1002/ceat.200600286 |
| Kurzbeschreibung (Abstract): | It is investigated whether the catalyst system Ag-In/SiO₂ can be applied in the selective hydrogenation of citral, with the aim of synthesizing the acyclic, allylic terpene alcohols geraniol/nerol with high selectivity and space-time yield. In addition, as liquid-phase hydrogenations are often also influenced by the choice of solvent, it is of interest to know how the solvent, in particular in terms of its polarity and hydrogen solubility, affects the activity and the selectivity of catalysts during hydrogenation of the α,β-unsaturated aldehyde citral. |
| Freie Schlagworte: | Catalysts • Hydrogenation • Solvents |
| Zusätzliche Informationen: | Published Online: 21. März 2007 |
| Fachbereich(e)/-gebiet(e): | 07 Fachbereich Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie > Technische Chemie II 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Technische Chemie |
| Hinterlegungsdatum: | 20 Mär 2009 09:00 |
| Letzte Änderung: | 05 Mär 2013 09:18 |
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