Plenio, Herbert ; Kaps, Alexander ; Foro, Sabine (2022)
Bi- and trimetallic complexes with macrocyclic xanthene-4,5-diNHC ligands.
In: Dalton Transactions, 51 (6)
doi: 10.1039/D1DT03857E
Artikel, Bibliographie
Kurzbeschreibung (Abstract)
Three different types of bimetallic NHC-metal complexes were synthesized, whose NHC units are attached at the 4,5-positions of xanthene. The NHC units are in close proximity and are designed such that each carbene coordinates one ML unit, while the chelation of one metal by two NHC is not possible. Several xanthene-((NHC)ML)2 complexes with ML = RhCl(cod), IrCl(cod), RhCl(CO)2, IrCl(CO)2, AuCl, AgCl, CuCl and Pd(allyl)Cl were synthesized and investigated.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2022 |
| Autor(en): | Plenio, Herbert ; Kaps, Alexander ; Foro, Sabine |
| Art des Eintrags: | Bibliographie |
| Titel: | Bi- and trimetallic complexes with macrocyclic xanthene-4,5-diNHC ligands |
| Sprache: | Englisch |
| Publikationsjahr: | 20 Januar 2022 |
| Verlag: | Royal Society of Chemistry |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Dalton Transactions |
| Jahrgang/Volume einer Zeitschrift: | 51 |
| (Heft-)Nummer: | 6 |
| DOI: | 10.1039/D1DT03857E |
| URL / URN: | https://pubs.rsc.org/en/content/articlehtml/2022/dt/d1dt0385... |
| Kurzbeschreibung (Abstract): | Three different types of bimetallic NHC-metal complexes were synthesized, whose NHC units are attached at the 4,5-positions of xanthene. The NHC units are in close proximity and are designed such that each carbene coordinates one ML unit, while the chelation of one metal by two NHC is not possible. Several xanthene-((NHC)ML)2 complexes with ML = RhCl(cod), IrCl(cod), RhCl(CO)2, IrCl(CO)2, AuCl, AgCl, CuCl and Pd(allyl)Cl were synthesized and investigated. |
| Fachbereich(e)/-gebiet(e): | 07 Fachbereich Chemie 07 Fachbereich Chemie > Eduard Zintl-Institut > Fachgebiet Anorganische Chemie 07 Fachbereich Chemie > Eduard Zintl-Institut > Fachgebiet Anorganische Chemie > Organometallchemie |
| Hinterlegungsdatum: | 16 Dez 2022 07:03 |
| Letzte Änderung: | 16 Dez 2022 07:03 |
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