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Synthese und Molekülstruktur von [alpha-(Dichlormethylsilyl)ethyl] dichlorborandimethylsulfid

Ruwisch, Lutz M. and Riedel, R. and Klingebiel, U. and Noltemeyer, M. (1999):
Synthese und Molekülstruktur von [alpha-(Dichlormethylsilyl)ethyl] dichlorborandimethylsulfid.
In: Zeitschrift für Naturforschung, 54 (5), pp. 624-626, [Article]

Abstract

[�-(Dichloromethylsilyl)ethyl]-dichloroborane-dimethylsulfide has been synthesized by the reaction of dichloromethylvinylsilane with dichloroborane-dimethylsulfide and its molecular structure determined by single crystal X-ray diffraction and by spectroscopic methods. Following the Markovnikov rule, a chiral methine group is formed as a bridge between silicon and boron.

Item Type: Article
Erschienen: 1999
Creators: Ruwisch, Lutz M. and Riedel, R. and Klingebiel, U. and Noltemeyer, M.
Title: Synthese und Molekülstruktur von [alpha-(Dichlormethylsilyl)ethyl] dichlorborandimethylsulfid
Language: German
Abstract:

[�-(Dichloromethylsilyl)ethyl]-dichloroborane-dimethylsulfide has been synthesized by the reaction of dichloromethylvinylsilane with dichloroborane-dimethylsulfide and its molecular structure determined by single crystal X-ray diffraction and by spectroscopic methods. Following the Markovnikov rule, a chiral methine group is formed as a bridge between silicon and boron.

Journal or Publication Title: Zeitschrift für Naturforschung
Volume: 54
Number: 5
Uncontrolled Keywords: Silicon, Silylethyl-boranedimethylsulfide, Crystal Structure
Divisions: 11 Department of Materials and Earth Sciences
11 Department of Materials and Earth Sciences > Material Science
11 Department of Materials and Earth Sciences > Material Science > Dispersive Solids
Date Deposited: 19 Nov 2008 16:23
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