Loesch-Zhang, Amelia ; Cordt, Cynthia ; Geissler, Andreas ; Biesalski, Markus (2022)
A Solvent-Free Approach to Crosslinked Hydrophobic Polymeric Coatings on Paper Using Vegetable Oil.
In: Polymers, 2022, 14 (9)
doi: 10.26083/tuprints-00021376
Artikel, Zweitveröffentlichung, Verlagsversion
Kurzbeschreibung (Abstract)
Hydrophobic coatings are of utmost importance for many applications of paper-based materials. However, to date, most coating methods demand vast amounts of chemicals and solvents. Frequently, fossil-based coating materials are being used and multiple derivatization reactions are often required to obtain desired performances. In this work, we present a solvent-free paper-coating process, where olive oil as the main biogenic component is being used to obtain a hydrophobic barrier on paper. UV-induced thiol-ene photocrosslinking of olive oil was pursued in a solvent-free state at a wavelength of 254 nm without addition of photoinitiator. Optimum reaction conditions were determined in advance using oleic acid as a model compound. Paper coatings based on olive oil crosslinked by thiol-ene reaction reach water contact angles of up to 120°. By means of Fourier transform infrared spectroscopy and differential scanning calorimetry, a successful reaction and the formation of a polymer network within the coating can be proven. These results show that clickchemistry strategies can be used to achieve hydrophobic polymeric paper coatings while keeping the amount of non-biobased chemicals and reaction steps at a minimum.
| Typ des Eintrags: | Artikel |
|---|---|
| Erschienen: | 2022 |
| Autor(en): | Loesch-Zhang, Amelia ; Cordt, Cynthia ; Geissler, Andreas ; Biesalski, Markus |
| Art des Eintrags: | Zweitveröffentlichung |
| Titel: | A Solvent-Free Approach to Crosslinked Hydrophobic Polymeric Coatings on Paper Using Vegetable Oil |
| Sprache: | Englisch |
| Publikationsjahr: | 2022 |
| Publikationsdatum der Erstveröffentlichung: | 2022 |
| Verlag: | MDPI |
| Titel der Zeitschrift, Zeitung oder Schriftenreihe: | Polymers |
| Jahrgang/Volume einer Zeitschrift: | 14 |
| (Heft-)Nummer: | 9 |
| Kollation: | 13 Seiten |
| DOI: | 10.26083/tuprints-00021376 |
| URL / URN: | https://tuprints.ulb.tu-darmstadt.de/21376 |
| Zugehörige Links: | |
| Herkunft: | Zweitveröffentlichung aus gefördertem Golden Open Access |
| Kurzbeschreibung (Abstract): | Hydrophobic coatings are of utmost importance for many applications of paper-based materials. However, to date, most coating methods demand vast amounts of chemicals and solvents. Frequently, fossil-based coating materials are being used and multiple derivatization reactions are often required to obtain desired performances. In this work, we present a solvent-free paper-coating process, where olive oil as the main biogenic component is being used to obtain a hydrophobic barrier on paper. UV-induced thiol-ene photocrosslinking of olive oil was pursued in a solvent-free state at a wavelength of 254 nm without addition of photoinitiator. Optimum reaction conditions were determined in advance using oleic acid as a model compound. Paper coatings based on olive oil crosslinked by thiol-ene reaction reach water contact angles of up to 120°. By means of Fourier transform infrared spectroscopy and differential scanning calorimetry, a successful reaction and the formation of a polymer network within the coating can be proven. These results show that clickchemistry strategies can be used to achieve hydrophobic polymeric paper coatings while keeping the amount of non-biobased chemicals and reaction steps at a minimum. |
| Status: | Verlagsversion |
| URN: | urn:nbn:de:tuda-tuprints-213766 |
| Zusätzliche Informationen: | This article belongs to the Special Issue Feature Papers in Polymer Applications (siehe verwandtes Werk) Keywords: vegetable oil; coatings; paper; thiol-ene; hydrophobicity; barrier; food packaging |
| Sachgruppe der Dewey Dezimalklassifikatin (DDC): | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Fachbereich(e)/-gebiet(e): | 07 Fachbereich Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Makromolekulare Chemie 07 Fachbereich Chemie > Ernst-Berl-Institut > Fachgebiet Makromolekulare Chemie > Makromolekulare Chemie und Papierchemie |
| Hinterlegungsdatum: | 24 Mai 2022 10:14 |
| Letzte Änderung: | 25 Mai 2022 05:48 |
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