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Characterization and application of a novel low viscosity polysilazane for the manufacture of C- and SiC-fiber reinforced SiCN ceramic matrix composites by PIP process

Mainzer, Bernd ; Lin, Chaorong ; Jemmalia, Raouf ; Friess, Martin ; Riedel, Ralf ; Koch, Dietmar (2019)
Characterization and application of a novel low viscosity polysilazane for the manufacture of C- and SiC-fiber reinforced SiCN ceramic matrix composites by PIP process.
In: Journal of the European Ceramic Society, 39 (2-3)
doi: 10.1016/j.jeurceramsoc.2018.09.042
Artikel, Bibliographie

Kurzbeschreibung (Abstract)

Four unidirectional fiber reinforced SiCN ceramic matrix composites were manufactured by means of polymer infiltration and pyrolysis. Two carbon fibers (T800H and Granoc XN90) as well as two silicon carbide fibers (Tyranno ZMI and SA3) without fiber coating were chosen. As matrix precursor, a poly(methylvinyl)silazane was investigated and utilized. The composites with the SA3 and the XN90 fiber had the highest tensile strengths of 478 and 288 MPa, respectively. It is considered that these high modulus fibers with the low modulus SiCN matrix create weak matrix composites. After exposure to air (T = 1200 degrees C, 10 h), a significant decrease of the mechanical properties was found, caused by the burnout of carbon fibers and the oxidation through open pores stemming from the PIP process and SiCN/SiCN interfaces in case of the SiC fiber based composites.

Typ des Eintrags: Artikel
Erschienen: 2019
Autor(en): Mainzer, Bernd ; Lin, Chaorong ; Jemmalia, Raouf ; Friess, Martin ; Riedel, Ralf ; Koch, Dietmar
Art des Eintrags: Bibliographie
Titel: Characterization and application of a novel low viscosity polysilazane for the manufacture of C- and SiC-fiber reinforced SiCN ceramic matrix composites by PIP process
Sprache: Englisch
Publikationsjahr: Februar 2019
Verlag: Elsevier Science Ltd, England
Titel der Zeitschrift, Zeitung oder Schriftenreihe: Journal of the European Ceramic Society
Jahrgang/Volume einer Zeitschrift: 39
(Heft-)Nummer: 2-3
DOI: 10.1016/j.jeurceramsoc.2018.09.042
URL / URN: https://www.sciencedirect.com/science/article/abs/pii/S09552...
Kurzbeschreibung (Abstract):

Four unidirectional fiber reinforced SiCN ceramic matrix composites were manufactured by means of polymer infiltration and pyrolysis. Two carbon fibers (T800H and Granoc XN90) as well as two silicon carbide fibers (Tyranno ZMI and SA3) without fiber coating were chosen. As matrix precursor, a poly(methylvinyl)silazane was investigated and utilized. The composites with the SA3 and the XN90 fiber had the highest tensile strengths of 478 and 288 MPa, respectively. It is considered that these high modulus fibers with the low modulus SiCN matrix create weak matrix composites. After exposure to air (T = 1200 degrees C, 10 h), a significant decrease of the mechanical properties was found, caused by the burnout of carbon fibers and the oxidation through open pores stemming from the PIP process and SiCN/SiCN interfaces in case of the SiC fiber based composites.

Freie Schlagworte: SiC/SiCN; C/SiCN; Polysilazane; PIP; Interface MULTILAYERED INTERPHASES; MECHANICAL-PROPERTIES; SIC/SIC COMPOSITE; CARBON-FIBERS; N CERAMICS; BEHAVIOR; (PYC/SIC)(N)
Fachbereich(e)/-gebiet(e): 11 Fachbereich Material- und Geowissenschaften
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft
11 Fachbereich Material- und Geowissenschaften > Materialwissenschaft > Fachgebiet Disperse Feststoffe
Hinterlegungsdatum: 03 Dez 2018 14:49
Letzte Änderung: 03 Dez 2018 14:49
PPN:
Sponsoren: Bundesministerium fur Bildung und Forschung (Germany) , Grant Number 03EK3544
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